首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   20356篇
  免费   3106篇
  国内免费   3134篇
化学   16332篇
晶体学   394篇
力学   894篇
综合类   228篇
数学   2164篇
物理学   6584篇
  2024年   20篇
  2023年   338篇
  2022年   498篇
  2021年   705篇
  2020年   864篇
  2019年   919篇
  2018年   685篇
  2017年   759篇
  2016年   951篇
  2015年   1042篇
  2014年   1269篇
  2013年   1604篇
  2012年   1834篇
  2011年   1954篇
  2010年   1439篇
  2009年   1330篇
  2008年   1586篇
  2007年   1284篇
  2006年   1206篇
  2005年   998篇
  2004年   792篇
  2003年   667篇
  2002年   775篇
  2001年   538篇
  2000年   421篇
  1999年   329篇
  1998年   254篇
  1997年   190篇
  1996年   191篇
  1995年   177篇
  1994年   156篇
  1993年   136篇
  1992年   101篇
  1991年   109篇
  1990年   74篇
  1989年   88篇
  1988年   43篇
  1987年   47篇
  1986年   43篇
  1985年   57篇
  1984年   30篇
  1983年   23篇
  1982年   12篇
  1981年   15篇
  1980年   9篇
  1979年   6篇
  1978年   5篇
  1977年   6篇
  1976年   5篇
  1957年   4篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
In this paper, multi-objective models for designing 3D trajectory of horizontal wells are developed in a fuzzy environment. Here, the objectives of minimizing the length of the trajectory and the error of entry target point are fuzzy in nature. Some parameters, such as initial value, end value, lower bound and upper bound of the curvature radius, tool-face angle and the are length of each curve section, are also assumed to be vague and imprecise. The impreciseness in the above objectives have been expressed by fuzzy linear membership functions and that in the above parameters by triangular fuzzy numbers. Models have been solved by the fuzzy non-linear programming method based on Zimmermann [1] and Lee and Li [2]. Models are applied to practical design of the horizontal wells. Numerical results illustrate the accuracy and efficiency of the fuzzy models.  相似文献   
92.
A novel measurement method of temperature based on the phenomena that the phase difference between principle polarization states in the optical retarder is function of temperature is described. The polarization state of optical beam is changed as it passes through the optical retarder, which depends on the temperature. The temperature of optical retarder is determined by comparison of the power difference between principal polarization states. We demonstrate successfully the temperature measurement by using a polarization maintaining fiber as the optical retarder. With a 100 mm length of the fiber optic retarder, the change rate of phase difference on temperature was 0.236 rad/°C and the measurement error was ±0.038°C over the temperature range of −2.6 – +3.4°C. With a 11.5 mm length of the fiber optic retarder, the change rate of phase difference on temperature was 0.021 rad/°C and the measurement error was ±0.79°C over the temperature range of −8.5 – +86.5°C.  相似文献   
93.
Ji  Min  Sun  Deyan  Gong  Xingao 《中国科学 数学(英文版)》2004,47(1):92-100

A new constant-pressure molecular dynamics (MD) method is developed to simulate the dynamic behavior and structure transition of finite system under external pressure. In this method, no artificial parameter is introduced and the computation overheads are very small. As an application, a hard-soft transition of single wall carbon nanotube (SWCNT) under external pressure is found, which is in agreement with the experiments.

  相似文献   
94.
5‐Methylene‐2‐oxazolidinone (1) and 5‐methylene‐1,3‐thiazolidine‐2‐thione (4) react with various isocyanates to give the corresponding urethanes 3 and 5 in high yields in the presence of palladium(0) or palladium(II) catalyst under mild reaction conditions. A mechanism is proposed. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
95.
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous.  相似文献   
96.
A series of new 1H‐pyrazolo[3,4‐d]pyrimidin‐4(5H)‐one Derivatives 5 has been designed and regio‐selectively synthesized via a tandem aza‐Wittig reaction. The structures of all compounds prepared have been confirmed by 1H NMR, IR, EI‐MS spectroscopy and elemental analyses. The results of preliminary bioassay indicate that most compounds 5 possess an inhibition effect against Botrytis cinereapers and Pyricularia oryzae at the concentration of 50 mg/L.  相似文献   
97.
张胜海  杨华  钱兴中 《物理学报》2004,53(11):3706-3709
提出一种非线性延时反馈参数调制法来控制混沌/超混沌,给出了利用这种方法控制处于超混沌状态的双环掺铒光纤激光器的方案.数值模拟表明,只要延时时间和反馈强度合适就可以把双环掺铒光纤激光器从超混沌状态成功地控制到不同的周期状态. 关键词: 掺铒光纤激光器 超混沌 非线性延时反馈参数调制 混沌控制  相似文献   
98.
By making use of a light gas gun, a specially designed target is impacted by the LY12 flyer, and the pressure is taken in the range of 0.6-3 GPa. Based on the stress profiles measured in the buffer materials by manganese gauges, the Hugoniot curve and release curves of LY12 aluminium alloy are obtained. Meanwhile, the release curves from different initial shocked states are described in both the pressure-particle velocity plane and the pressure-specific volume plane.  相似文献   
99.
Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO2 structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2. Indeed, Li[Ni0.50Mn0.50]O2 compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni0.17Li0.22Mn0.61]O2 and Li[Ni0.25Li0.17Mn0.58]O2 compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni2+ and about Ni3+, while the oxidation state of Mn ion sustains Mn4+ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2, in which Ni ion changes between Ni2+ and NI4+. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process.  相似文献   
100.
In this paper a simple and convenient new regularization method for solving backward heat equation—Fourier regularization method is given. Meanwhile, some quite sharp error estimates between the approximate solution and exact solution are provided. A numerical example also shows that the method works effectively.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号